Bio-psychological Medicine - BJSTR Journal

Abstract

The #linear combination f₁₂ = 2 f(O) - f(H) of elemental balances: f¹ = f(H) for H and f₂ = f(O) for O is the keystone in formulation of #Generalized Electron Balance (GEB), which completes the set of equations necessary for resolution of an electrolytic redox system according to Approach II to GEB in aqueous media. The f does not involve the numbers of free and hydrating water molecules. The linear dependency or independency of f₁₂ from charge balance (f₀ = ChB) and other elemental/core balances f_k = f(Y_k) (k=3...,K) for elements/cores Y_k of the system is the general criterion distinguishing between non-redox and redox systems. This criterion is provided by linear combination where K* (≤K) is the number of electron-non-active elements (fans) of the system, and dk are the multipliers related to oxidation numbers (ONs) of the elements involved in Y_k. For non-redox systems, LC is transformed into identity, 0 = 0, whereas for #redox systems, the LC and each linear combination are different from identity. The ONs, reductant, oxidant are derivative concepts in this formulation. All these interesting regularities are illustrated by #simulated titration in a #symproportionating redox system, resolved according to Generalized Approach to Electrolytic Systems (GATES) principles.

For more articles on BJSTR Journal please click on https://biomedres.us/

For more Bio-psychological Medicine Articles on BJSTR

https://biomedres.us/fulltexts/BJSTR.MS.ID.001591.php

The Distinguishing Role of 2.f(O) - f(H) in Electrolytic Systems by Tadeusz Micha∤owski in BJSTR