Wednesday, January 23, 2019

Tabular Organisation of Ionothermally Prepared MOFs To Extrapolate Chemical Trends and Successfully Predict #Synthesis Results by Eun Young Choi in BJSTR

#Metalorganic frameworks, or MOFs, have a strength over other classes of materials in which the constituents of the frameworks may be chosen among the vast range of #organicligands and metals, and such combination leads to nearly infinite possibility of novel frameworks. This freedom of choices expands when the variety of #synthesis methods for MOFs is considered. Ionothermal synthesis, which makes use of ionic liquids for both the purpose of solvent and template, is a relatively recently introduced method that best exercises such potential on its own [1], along with many advantages like safety, which is associated with the low #vapourpressure of #ionicliquids [2], #thermalstability [3], and safety in environmental means relative to its organic predecessors [4]. The cation and anion that comprises the ionic solvent used in the method may be easily substituted with their close chemical relatives, chloride with another #halide for example, and finely tune the reaction environment.

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